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  IZMIR INSTITUTE OF TECHNOLOGY
RESEARCH PROJECTS OF THE YEAR 2000

Biçimsel Seçimli Katalizörlerin C-C Kenetlenme ve Katılma Tepkimelerinde Uygulamaları

Project No 2000 FEN 01
Director of the Project Assoc. Prof. Dr. LEVENT ARTOK
Researchers Hatice Güllübağ, Assist Prof. Dr. Selahattin Yılmaz, Prof. Dr. Semra Ülkü
Faculty/Department Faculty of Science, Department of Chemistry
Project Term 2 years

The Aim, the Signaficance, and the Expected Outcomes of the Project:
     Electrophilic and nucleophilic substitution, addition, and isomerization reactions are the reactions types that are commonly applied to synthesise building blocks of numerous pharmaceuticals, pesticides, polymers and fragrances. Catalysts used in these reactions are mainly mineral acids and bases and these reactions are typically carried out in liquid or gaseous phases. Mineral acids and bases may cause various complications in industrial scale applications. These acids also do not have regio-, chemo- and enantiomeric selectivity. Recovery of these mineral agents is rather difficult and they are also environmentally detrimental However, heterogeneous solid catalysts are relatively easy to handle and posses no environmental drawback. In this study molecular shape selective porous solid catalysts, such as synthetic and natural zeolites, and molecular sieves will be tested in their applicability in the reactions stated above.